Organic Chemistry

• Photo-induced energy transfer mediated O2-initiated deboronative generation of alkyl radicals from alkyl boronic acids and its application in radical Smiles rearrangement

  Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QO00323G, Research ArticleJinpeng Wu, Yongsheng Tian, Xue Zhao, Shuai Liu, Liang Xu, Huanhuan SongA visible-light-induced, energy-transfer me...

  2025-04-03 23:00:00

• Enantioselective C–H Amidation of Sulfondiimines for the Synthesis of 1,2,4-Benzothiadiazine-1-Imines under Cobalt Catalysis

  Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QO00355E, Research Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ayami Mur...

  2025-04-03 23:00:00

• Metal and photocatalyst-free alkylboration of [1.1.1]propellane enabled by red-light-induced electron transfer

  Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QO00357A, Research ArticleYuying Wang, Jianyang Dong, Yulin Xiao, Zhilin Wang, Weilin Wu, Dong XueHighly strained 1,3-disubstituted bicyclo[1...

  2025-04-03 23:00:00

• Garynthone A–I, PPAPs with diverse skeletons isolated from Garcinia yunnanensis and their immunosuppressive activity

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00414D, Research ArticleZifeng Guo, Pengxue Ji, Shengnan Yang, Zhiyuan Li, Yongbo Yu, Jingming Jia, Anhua WangGarynthone A (1), the first caged...

  2025-04-03 23:00:00

• Thrysaxinones A−F: antibacterial phloroglucinol−terpenoid adducts from Thryptomene saxicola

  Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QO00172B, Research ArticleWei-Fang Su, Ni-Ping Li, Rui-Qin Cui, Fen Liu, Mu Chen, Xin-Yue Wu, Min-Jing Cheng, Jia-Qing Cao, Wei Huang, Xiaoqi...

  2025-04-02 23:00:00

• NHC and photoredox co-catalyzed 1,4-alkylcarbonylation of 1,3-enynes

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D4QO02311K, Research ArticleZhaoyang Zhang, Jia-Yi Yang, Shihao Li, Xiao-Xuan Li, Yi-Si FengA strategy to obtain 1,2-alkenyl ketone products by rad...

  2025-04-02 23:00:00

• Multistimuli-Responsive and Multimode Azoquinoline Chiroptical Switches

  Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QO00469A, Research ArticleZimu Liu, Youming Lv, Hebo Ye, Hanwei Lu, Lei YouChiroptical switches combine molecular switches and chiral signali...

  2025-04-02 23:00:00

• Light induced interrupted alkene diiodination with carbon atom insertion: Access to trifluoromethylated 1,3-diiodoalkanes†

  Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QO00358J, Research ArticleTengfei Pang, Yu Yan, Jianjian Huang, Fangrui Zhong, Guojiao WuIn contrast to the well-established 1,2-dihalogenati...

  2025-04-02 23:00:00

• CPL-Tunable BN-Embedded Supramolecular Macrocycles

  Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QO00274E, Research ArticleYu-Chi Dai, Yun-Tao Ding, Jin-Lin Qing, Wei-Ning Zhang, Zhi-Qiang Zhang, Xuefeng Zhu, Jing-Jing Cao, Chunlin Sun, X...

  2025-04-01 23:00:00

• An Efficient Total Synthesis of (+)-Entecavir

  Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QO00329F, Research ArticleChenlong Zhu, Nanlian Li, Yaopeng Ma, Bingfeng SunAn efficient asymmetric total synthesis of entecavir was accompli...

  2025-04-01 23:00:00

• Unraveling the Divergent Mode of Cu- or Zn-assisted Radical Addition of Imine: A Mechanistic Perspective on Lewis Acidic Metal-Induced enantioselectivity

  Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QO00530B, Research ArticleDongmin Fu, Ruopeng Bai, Jiang Wu, Kai Yang, Xiaokang Guo, Yu Lan, Tao ZhangAs widely used Lewis acidic metals, Cu...

  2025-04-01 23:00:00

• Photoinduced diversity-oriented synthesis of α-ketoester β-enamino esters, 3,3-difluoro-4-pyrrolin-2-ones, and 3-fluoro-3-pyrrolin-2-ones from bromodifluoroacetates and β‐enamino esters

  Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QO00050E, Research ArticleDewei Feng, Renhua Zheng, Zhifang Li, Xiao Geng, Lei WangDiversity-oriented synthesis (DOS) has emerged as a pivota...

  2025-04-01 23:00:00

• Rh(III)-catalyzed base-free α-arylation of iodonium ylides with arylboronic acids: modular synthesis of 5-aryl barbituric acids

  Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QO00259A, Research ArticleMengling He, Shuoying Cai, Nursemanguli Baiheti, Linmei Zhao, Huaming Tao, Shaoyu MaiTo date, the synthesis of 5-ar...

  2025-04-01 23:00:00

• Three-component, stereoselective C–N bond forming alkene difunctionalization

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00160A, Review ArticleJihoon Na, Je Uk Kim, Seonggyu Kim, Chanwoo Kim, Gayoung Lee, Sumin LeeThis review discusses emerging strategies in three...

  2025-04-01 23:00:00

• Recent advances in organocatalytic asymmetric multicomponent reactions

  Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QO00347D, Review ArticlePeng-Ying Jiang, San Wu, Jun Wang, Shao-Hua Xiang, Bin TanMulticomponent reactions enable the simultaneous formation...

  2025-04-01 23:00:00

• Dimethoxytetramethyldisilane: overcoming the limitations of palladium-catalyzed C-H silacyclization of 2-iodobiphenyls

  Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QO00249D, Research ArticleZhengrui Zhou, Xuliang Tan, Shuyun Peng, Yun Liang, Yuan YangHerein, a readily accessible silicon reagent (dimethox...

  2025-03-31 23:00:00

• A mechanochemical addition/reduction cascade process for the synthesis of dual stereocentered chiral δ-hydroxysulfones

  Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO02158D, Research ArticleYongjin Zhang, Yanwen Gong, Donghua He, Tianqi Xu, Binhong Jiang, Kun Zhang, Guohua LiuThe development of mechanoch...

  2025-03-31 23:00:00

• Photore-dox/Nickel Du-al-Catalyzed Re-gio- and Stereo-selective Cross-Coupling of Allyl Trifluoroborates with Alkenyl Electrophiles: Synthesis of 1,4-Dienes

  Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QO00317B, Research ArticlePeizhuo Lv, Xin Xie, Yuanhong LiuA mild photoredox/Nickel dual-catalyzed cross-coupling of allyl trifluoroborates w...

  2025-03-31 23:00:00

• Palladium-catalysed asymmetric regioselective hydroamination of dienoates

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00402K, Research ArticleBao-Xin Liu, Xin-Ting Qin, Shi-Cun Li, Lei Zhu, Qin Ouyang, Wei Du, Ying-Chun ChenAn asymmetric formal 1,4-Michael addi...

  2025-03-30 00:00:00

• A DFT Investigation on the Mechanism of Photoinduced Radical Borylation of Alkyl Bromides: Elucidation for Base-Mediated Photoinduced SET and SN2 Processes

  Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QO00048C, Research ArticleNana Ma, Qiongjin Wang, Die Zhao, Bowen Duan, Shujun Li, Guisheng ZhangThe transition-metal-free borylation of alky...

  2025-03-29 00:00:00

• Copper-mediated divergent synthesis of halogenated 1-pyrrolines, 3-azabicyclo[3.1.0]hex-2-enes and α,α-dibromo imines from N-allyl enamines

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00217F, Research ArticleXiyan Duan, Junqi Wang, Kun Liu, Fengjiao Du, Maoling He, Wenxin Li, Xinming Liu, Pu LiuChemodivergent synthesis of hal...

  2025-03-29 00:00:00

• Construction of chiral γ-lactam scaffolds via asymmetric cascade [3+2] annulation of N-alkoxyacrylamides catalyzed by a chiral-at-metal rhodium complex

  Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QO00276A, Research ArticleWan-Shun Cheng, Yong-Bing Ke, Yang Chen, Hui-Ting Cui, Rui-Qiu Zhang, Helin Lu, Ping Xue, Xiaobo Wang, Shi-Wu Li, J...

  2025-03-29 00:00:00

• Catalytic (5+1) Cycloaddition of Diazooxindoles with Imidazolidines to Access Novel Piperazine-Spirooxindole Frameworks

  Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QO00361J, Research ArticleYijun Duan, Feng Chen, Yuncheng Liu, Wendi Xu, Xue Zhang, Ming Lang, Shiyong PengHerein, a catalytic (5+1) cycload...

  2025-03-28 00:00:00

• Fe-Catalyzed B-H and N-H Insertion Reactions of Iodonium Ylides

  Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01916D, Research ArticleHejun An, Zhi Cui, Jinchao Liang, Xingxing Ma, Jinglong Chen, Qiuling SongThe difunctionalization of olefins as an...

  2025-03-28 00:00:00

• Asymmetric oxidative rearrangement of indoles enabled by dual catalysis with in situ generated acyl hypoiodite and chiral phosphoric acid

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00302D, Research ArticleHaowei Gao, Xihui Yang, Lei ShiA dual catalytic asymmetric oxidative rearrangement of indoles via traceless halonium in...

  2025-03-28 00:00:00

• Solvent-controlled 4CzBnBN-catalyzed intramolecular photocyclization and dehydrogenative photocyclization of indole carboxamides for the switchable synthesis of indoloquinolones and dihydroindoloquinolones

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00185D, Research ArticleYihao Zhang, Peng Zhang, Hang Zhao, Xing Wang, Xia Zhou, Yimou Gong, Lin Wang, Siping Wei, Zhijie Zhang, Qiang FuWe hav...

  2025-03-28 00:00:00

• EDA complex photochemistry as a strategy for C–S bond formation

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00258C, Review Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.H...

  2025-03-28 00:00:00

• Palladium-catalyzed Z-alkenylative cross-coupling via β-alkenyl elimination of Z-allylic alcohols

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00110B, Research ArticleXue-Mei Huang, Cheng Liang, Si-Qi Xiong, Xue Zhang, Kai-Xian Ma, Qing-Hua Li, Tang-Lin LiuThe Z-alkenylative cross-coup...

  2025-03-28 00:00:00

• Visible-light-induced radical cascade cyclization of 2-isocyanobiaryls via 1,5-hydrogen atom transfer (1,5-HAT)

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00031A, Research ArticleYafei Zhu, Penghua Zhang, Xingqin Tian, Xueqin Wang, Mi Wang, Cuimei Zhang, Jian Chen, Jing Zhang, Guanghui Lv, Yong Wu...

  2025-03-27 00:00:00

• Iron-catalyzed regioselective carboazidation of alkenes for the synthesis of multi-substituted cyclobutylamines

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00173K, Research ArticleYufei Li, Yajun Li, Hongli BaoAn iron-catalyzed carboazidation of alkenes for the regioselective synthesis of multi-sub...

  2025-03-27 00:00:00

• Photoredox-catalyzed three-component alkylation of glycine derivatives and peptides via a site-selective 1,5-hydrogen atom transfer cascade

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00294J, Research ArticleHongying Fan, Liulin Jiao, Ting Yuan, Jian Chen, Qingyun Gu, Xue Zhang, Jinyu Hou, Zhongzhen Yang, Li Guo, Yong WuWe re...

  2025-03-27 00:00:00

• 8,14-seco-ent-Kaurane Diterpenoids from Isodon glutinosus: Enol-Enol Tautomerism and Antitumor Activity

  Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QO00356C, Research ArticleYang-Yang Fu, Kun Hu, Song-Yu Hou, Bing-Chao Yan, Xiao-Nian Li, Xing-Zhi Yang, Han-Dong Sun, Pema-Tenzin PunoGlut...

  2025-03-27 00:00:00

• Unveiling stereoselective ladders via photo-oligomerization of a diazaanthracene macrocycle

  Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QO00159E, Research ArticleJinti Moni Kumar, Ivan Huc, Yann Ferrand, Bappaditya GoleWe present an efficient light-driven oligomerization of fl...

  2025-03-25 00:00:00

• Copper-catalyzed anti-stereoselective 1,2-silylamination of alkynes

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00040H, Research ArticleKelu Yan, Xiaoyu Wang, Jiangwei Wen, Qiuyun Li, Jianjing Yang, Xinru Tao, Shenghao Pan, Haosheng Liang, Xiu WangA coppe...

  2025-03-25 00:00:00

• Carbene-catalyzed imine reductive reaction: a new application of Breslow intermediates

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00332F, Research ArticleHui Zhu, Han Xiao, Lihe Wang, Bo Jiang, Qingyun Wang, Shuquan Wu, Pengcheng ZhengHere, we report a new NHC-catalyzed im...

  2025-03-25 00:00:00

• Metallaphotoredox-enabled enantioselective aryldifluoromethyl-alkynylation of alkenes via C(sp3)–F bond activation

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00370A, Research ArticleJialin Huang, Liying Fu, Xiaofei Zhao, Xingda Zhao, Zhanyong Tang, Xiaoqiang Ma, Depeng ZhaoEnantioselective aryldifluo...

  2025-03-25 00:00:00

• A Cu/Cd-cocatalysed cascade reaction for constructing nitrogen-tethered 1,6-enynes enabled by 1,5-hydride transfer

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00174A, Research ArticleTiantian Zhang, Hexiang Wang, Liliang Huang, Junhai Huang, Huangdi FengA versatile multi-component protocol for modular...

  2025-03-24 00:00:00

• Ni-catalyzed regio- and diastereoselective syn-alkynylamination of unactivated alkenes with alkylamine sources

  Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QO00194C, Research ArticleYixuan Wan, Cong Lin, Yihuan Cheng, Liang ShenThe three-component alkynylamination of alkenes provides a prevalent...

  2025-03-24 00:00:00

• Intramolecular and intermolecular benzannulation of arylethanone derivatives enabled by visible light-induced catalytic generation of tether-tunable distonic radical anions

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00271K, Research ArticleZhiyou Yu, Ziye Zhan, Kang Fu, Lei ShiA novel method enables inter-/intramolecular benzannulation to synthesize PAHs ha...

  2025-03-24 00:00:00

• Steroidal sapogenin-derived chirons: underdeveloped building blocks with methyl-branched chiral centers

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00090D, Review ArticleYu-Chuan Pu, Gen-Ying Liu, Ran Gao, Cheng-Yu HeThis review summarizes the application of steroidal sapogenin-derived lact...

  2025-03-23 00:00:00

• Recent advances in the diverse transformations of trifluoromethyl alkenes

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00306G, Review ArticleFei Liu, Qi Wu, Xin Wang, Qinghao Dong, Kai SunIn this paper, the diverse transformations of α-trifluoromethyl olefins, m...

  2025-03-23 00:00:00

• Single-atom editing for the construction of boron-containing heterocycles

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00210A, Review ArticleXue Li, Yi-Ming Chen, Zhi-Gang XuThis review provides a detailed examination of methods for synthesizing boron compounds,...

  2025-03-22 00:00:00

• Bromotrifluoromethoxylation of allenes: expedient access to allylic trifluoromethoxy derivatives

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D4QO02426E, Research ArticleRui Liu, Yangdong Hou, Pingping TangA mild and efficient method for the bromotrifluoromethoxylation of allenes has been...

  2025-03-22 00:00:00

• Condition-controlled selective synthesis of spiroisoquinolinones or spiroisoindolinones via CHA–initiated spiroannulation, ring opening and ring contraction

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00257E, Research ArticleYujing Xiao, Yuanshuang Xu, Shuya Zhang, Xinying Zhang, Xuesen FanPresented herein is a condition-controlled selective...

  2025-03-22 00:00:00

• Understanding the reaction mechanism of anti-addition of (NHC)Au(I)–H and (NHC)Au(I)–F across alkyne

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00432B, Research Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence...

  2025-03-21 00:00:00

• Deconstructive dicarbofunctionalization of cyclic amines enabled by C–H and C–N bond activation

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00270B, Research ArticleQiming Zhu, Kaifang Wang, Yuyuan Fan, Tianze Zhang, Xianchen Song, Shuang Luo, Qiang Zhu, Hanmin HuangA novel strategy...

  2025-03-21 00:00:00

• Enantioselective synthesis of α-functionalized phenylpyrrolidine via photo-enzymatic cascade multi-component reaction

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00169B, Research ArticleFengxi Li, Shenhan Xie, Wenxian Dong, Yihang Dai, Qikai Sun, Zhengqiang Li, Chuang Du, Zhi Wang, Lei WangCyclic amines...

  2025-03-21 00:00:00

• Supramolecular catalysis in the dearomative Michael addition involving nitro-group-activated benzofurans

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00035A, Research ArticleAleksandra Topolska, Artur Przydacz, Anna Skrzyńska, Łukasz AlbrechtThe manuscript presents supramolecular catalysis wi...

  2025-03-20 00:00:00

• Electrochemical oxidative one-pot difunctionalization of diazo compounds with triazoles and nucleophiles

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00333D, Research ArticleYaqi Deng, Jian Xue, Bajiba Bian, Shunying LiuA green difunctionalization of diazos through electrochemically enabled a...

  2025-03-20 00:00:00

• Palladium(II)-catalyzed enantioselective desymmetrization ring opening of oxabicyclic alkenes with alkynylanilines: efficient access to enantioenriched functionalized cyclohexenes

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00118H, Research ArticleBinhong Tan, Junjie Meng, Qianru Liu, Shixin Chen, Mingyue Xue, Yue Zhang, Yuping Zhang, Zhaodong LiEnantioselective Pd...

  2025-03-20 00:00:00

• Stable sulfonate esters as C1-synthons for cyclopropanation reaction to access antimicrobial active 3,3′-spirocyclopropyloxindoles

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00153F, Research ArticleYijie Long, Pinpin Feng, Hongyan Long, Yi Huang, Xingxing WuA NaH-mediated formal [2 + 1] annulation using stable while...

  2025-03-19 00:00:00

• Recent developments in organic synthesis for constructing carbon frameworks using transposition strategies

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00163C, Review ArticleSavita Narayanrao Gat, Piyusa Priyadarsan Pattanaik, Rambabu DandelaTransposition of molecular fragments enabling strateg...

  2025-03-19 00:00:00

• Phosphoric acid activation, reduction and transformation processes: efficient preparation of triarylphosphines

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00278H, Research ArticleYaling Tian, Tao Liu, Yao Chai, Zhibin Wang, Zhengyin Du, Xi-Cun Wang, Xiaofeng Wu, Zheng-Jun QuanIn this study, we dev...

  2025-03-19 00:00:00

• Fragmentation of glucosylphosphonium ylides for the synthesis of glycals

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00283D, Research ArticleChao Chen, Zhichao Mei, Mengyao You, Ziwei Zhang, Haiyang Huang, Qiang XiaoA formal homolysis of phosphonium ylide bond...

  2025-03-19 00:00:00

• Expedient access to α-(hetero)aryl-α-keto-1,3-diamines via redox-neutral photocatalyzed reactions of N-vinylimides with α-aminoalkyl radicals

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00239G, Research ArticleYu Zhao, Yutao Jing, Yan Li, Li Qiu, Yewen Fang1,3-Diamine synthesis: a new radical addition/acyl migration cascade pro...

  2025-03-18 00:00:00

• Update for oxidopyridinium cycloadditions and their synthetic applications: advances after Katritzky's pioneering studies

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00115C, Review Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Y...

  2025-03-18 00:00:00

• meta-OTf-substituted diaryliodonium salts enabled aryne 1,2,2′-trifunctionalization via a cascade of thia-Fries and aza-Claisen rearrangements

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00182J, Research ArticleLifeng Chu, Huangguan Chen, Zhen-Jiang Xu, Limin Wang, Jianwei HanA novel cascade reaction involving thia-Fries and aza...

  2025-03-17 00:00:00

• Total synthesis and structure revision of gonioheptenolactone

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00088B, Research ArticleJun Liu, Jingjing Bi, Yuxin Cui, Minhao Chen, Chuanfang Zhao, Wenting Li, Aishuang Zhan, Yuguo DuWe report the first to...

  2025-03-17 00:00:00

• Correction: A visible light-mediated three-component strategy based on the ring-opening of cyclic ethers with aryldiazoacetates and nucleophiles

  Org. Chem. Front., 2025, 12,2552-2553DOI: 10.1039/D5QO90022K, Correction Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Mateus L. Stivanin, Ra...

  2025-03-03 00:00:00

• Achievements in photocatalytic Povarov-type reactions: a key step in green diversification of the quinoline chemical space

  Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QO00099H, Review ArticleVladimir V. Kouznetsov, Fedor I. ZubkovThe advances in the Povarov reactions under visible-light conditions are highlight...

  2025-03-03 00:00:00

• Cycloisomerization of 7-en-2-yn-1-ones to bicyclo[3.1.0]hexanes using electrophilic fluorination or chlorination agents

  Org. Chem. Front., 2025, 12,2159-2164DOI: 10.1039/D4QO02373K, Research ArticleYuki Yasuda, Daisuke Sato, Akira Tsubouchi, Akio SaitoThis work represents the first report on the cycloisomerization of e...

  2025-02-19 00:00:00

• Zn-promoted Sandmeyer-type reductive chalcogenation of (hetero)aryl diazonium salts

  Org. Chem. Front., 2025, 12,2393-2400DOI: 10.1039/D5QO00103J, Research ArticleQiujin Fan, Yanchuang Zhao, Junhong Wang, Ying Bai, Shengbin Zhou, Xinxin ShaoIn this report, we describe a nickel-free, z...

  2025-02-18 00:00:00

• 5-Methylated polyprenylated acylphloroglucinol derivatives as low-voltage-gated Ca2+ channel inhibitors

  Org. Chem. Front., 2025, 12,2375-2381DOI: 10.1039/D4QO02233E, Research ArticleYa-Li Hu, Ding Dong, Jian-Jun Zhao, Kun Hu, Ling-Mei Kong, Yun-Xia Hu, Xing-Ren Li, Song-Yu Li, Yin Nian, Gang XuTwenty-se...

  2025-02-17 00:00:00

• Enantioselective modular synthesis of α-aryl-α-heteroaryl aminonitriles with parts per million organocatalyst loading: mechanistic investigation for stereochemical origins

  Org. Chem. Front., 2025, 12,2382-2392DOI: 10.1039/D4QO02362E, Research ArticleYusuke Oyamada, Kaito Ishikawa, Tsunayoshi Takehara, Takeyuki Suzuki, Shuichi NakamuraAn enantioselective Friedel-Crafts r...

  2025-02-17 00:00:00

• Recyclable g-C3N4 catalyzed decarboxylative alkenylation of N-aryl glycines with vinyl sulfones under visible-light irradiation

  Org. Chem. Front., 2025, 12,2409-2414DOI: 10.1039/D5QO00100E, Research Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ch...

  2025-02-14 00:00:00

• Recent advances in hydrofunctionalisation of cyclopropenes via carbon–heteroatom bond formation

  Org. Chem. Front., 2025, 12,2525-2551DOI: 10.1039/D4QO02441A, Review ArticleJorge García-Lacuna, Gema Domínguez, Ángel Manu Martínez, Javier Pérez-CastellsThis review highlights recent advances in the...

  2025-02-12 00:00:00

• Enantioselective synthesis of isoxazolines bearing allenes by palladium-catalyzed carboetherification of β,γ-unsaturated ketoximes with propargylic acetates

  Org. Chem. Front., 2025, 12,2305-2313DOI: 10.1039/D4QO02319F, Research ArticleFeifei Jin, Cangzhu Hu, Shuaijie Wu, Guodong Zhang, Ying Han, Chao-Guo Yan, Wenbo Li, Chaoshen Zhang, Lei WangEnantioselec...

  2025-02-11 00:00:00

• Self-photocatalysis with multiple activities: divergent synthesis of benzo[b]fluorenones and benzo[b]fluorenols from enone-ynes

  Org. Chem. Front., 2025, 12,2352-2361DOI: 10.1039/D4QO02444C, Research ArticleJifu Shi, Qingyao Sun, YunLing Gao, Yongqin Hu, Weili Li, Binbin He, Shulin Gao, Shaoguang Sun, Deqiang LiangPhotocatalyst...

  2025-02-11 00:00:00

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  2025-02-10 00:00:00

• Photoredox catalytic phosphine-mediated deoxygenative alkynylation of carboxylic acids with alkynyl sulfones for alkynone synthesis

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  2025-02-10 00:00:00

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  2025-02-08 00:00:00

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• Visible-light induced direct C(sp3)–H bond disulfidation of saturated N-heterocycles through a hydrogen atom transfer (HAT) process

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  2025-02-05 00:00:00

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  2025-02-05 00:00:00

• A transition-metal-free azide–alkyne cycloaddition/oxetane ring opening cascade reaction for the construction of hydroxymethyl decorated triazole-fused piperazin-2-ones and [1,4]diazepin-4-ones

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  2025-02-04 00:00:00

• A superior and accessible cavitand receptor for the binding of monoterpenes and sesquiterpenes in water

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  2025-02-04 00:00:00

• The influence of an acid additive on linear and branch selectivity in the C–H alkylation of N-pyridinecarbonyl-protected 2-methylbenzylamine with 1-heptene catalyzed by Rh2(OAc)4: a theoretical investigation

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  2025-02-01 00:00:00

• Photocatalytic selective disulfuration of aryl aldehydes and alkenyl aldehydes with dithiosulfonate as a bifunctional disulfur reagent and hydrogen atom acceptor

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  2025-02-01 00:00:00

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  2025-02-01 00:00:00

• Ligand-modulated phosphine-free Ni(II) complexes for Z-selective semi-transfer hydrogenation of alkynes and dual transfer hydrogenation of α,β-unsaturated ketones using ammonia borane

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  2025-01-31 00:00:00

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  2025-01-30 00:00:00

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  2025-01-29 00:00:00

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  2025-01-28 00:00:00

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  2025-01-28 00:00:00

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  2025-01-24 00:00:00

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  2025-01-24 00:00:00

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  2024-12-30 00:00:00

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  2024-09-17 23:00:00